Chemical Hybridization of CH3NH2 and the Polarity of its Lewis Structure

the CH3NH2 molecular weight is Methylamine’s molecular formula. This molecule has a lone pair of nitrogen atoms, making it obvious that this is a basic nitrogen molecule. The ammonia derivative methylamine is a colourless organic gaseous molecule.

It is also used commercially to generate ephedrine, carbofuran, metham sodium, methyl formamide, theophylline, carbaryl and N-methyl pyrrolidone. This chemical has a strong pungent fishy odour. Because it donates electron pairs when it forms bonds with electrophiles, methylamine is a well-known nucleophile and thus a Lewis base.

To produce a stable electrical state, Lewis bases act as a donor molecule, readily donating a pair of non-bonding electrons.

A Methylamine Lewis Crystal Structure (CH3NH2)

Diagrammatically, the Lewis structure depicts how valence electrons migrate to ensure bond formation. Lewis structure is the initial stage in chemical compound investigation because of its ability to identify the molecule’s grouping on the periodic table.

Formal charge on participating atoms and chemical bonding between atoms are studied using this feature, which favours covalent compounds the most. Resonance structures are formed when more than one Lewis diagram can be produced for a molecule.

To begin, it is essential to know how many valence electrons each participating element has in order to fully comprehend the Lewis structure of methylamine (CH3NH2). Carbon, with an atomic number of 6, has an electrical configuration of 1s2 2s2 2p2.

Carbon has four valence electrons because the p shell can only hold a maximum of six electrons. The electrical configurations of hydrogen and nitrogen are 1s1 and 2s2 2s2 2p1 because their atomic numbers are 1 and 7.

Hydrogen has a valence electron of one, while nitrogen has a valence electron of five since the s and p shells may each hold two valence electrons.

Let’s have a look at how to sketch the Lewis Structure of methylamine (CH3NH2), shall we?

Valence electrons in methylamine can be found using this formula: Four come from the carbon atom, one from each hydrogen atom, and five come from the nitrogen atom in a single methylamine (CH3NH2) molecule.

Step 2: Determine how many valence electrons a methylamine (CH3NH2) needs to have: One methylamine (CH3NH2) molecule has 12 valence electrons because each hydrogen atom requires one valence electron, while the carbon and nitrogen atoms each require four and three valence electrons.

The core atom of one methylamine (CH3NH2) molecule is to be found in this step. There are three hydrogen bonds to the carbon and two to the nitrogen from the chemical formula. As a result, the carbon and nitrogen atoms in CH3 and NH2 are two distinct things.

The methylamine (CH3NH2) atoms form a type of bond called a covalent bond. A lone pair of electrons on the nitrogen atom of methylamine (CH3NH2) forms a single bond with the other involved atoms.

Using the information from the previous steps, draw the structure.

Methylamine’s Molecular Structure and Function (CH3NH2)

Because of its dependence on the Lewis structure, molecular geometry can be used to calculate bond lengths, angles, and other geometrical factors based on the relative positions of the atoms involved.

Methylamine (CH3NH2) has two central atoms, hence the molecular geometry for both will be different because the bond angles are different for each central atom. The tetrahedral molecular shape of carbon predominantly targeting -CH3 is a result of bond angles of 109.5°. In contrast, because the bond angle is roughly 108.9° when targeting the -NH2 end of nitrogen, its molecular geometry is trigonal pyramidal.

This variation from the optimal percentage can be attributed to the existence of a lone pair of electrons on the nitrogen atom, which makes the ideal bond angle for trigonal pyramidal shape 109.5°.

The Valence Shell Electron Pair Repulsion (VSEPR) theory, which states that the lone pairs are present in the orbitals that are shorter and rounder than the orbitals with bonded pairs of electrons, can explain this.

As a result, the bond angle is reduced from its optimal proportion due to strong repulsion between the lone pair of electrons and the bonding pair.

Synthesis of Methylamines (CH3NH2)

New hybrid orbitals can be formed by mixing and matching atomic orbitals to create new hybrid orbitals, which alter the overall molecular shape and chemical bonding properties of the involved atoms.

The atomic orbitals with similar energies can engage in the hybridization process, which is inclusive of both filled and half-filled orbitals, according to quantum mechanics.

The methylamine (CH3NH2) is sp3 hybridised because the C-N sigma bond overlaps between the two sp3 orbitals, according to the Valence Bond Theory (VBT).

The centre atoms are said to be sp3 hybridised if they have sp3 hour hybrid orbitals. It is because of the overlap of the two sp3 hybridised orbitals with the hydrogen atoms’ s orbitals that two N-H bonds can be formed in this way.

To form a C-N sigma bond, the carbon atom’s sp3 hybridised orbital and the sp3 hybridised orbital of the nitrogen atom overlap and mix. The nitrogen atom’s only pair of electrons make up the fourth hybridised orbital.

Methylamine has polarity (CH3NH2)

The trait of polarity in chemical molecules allows them to choose whether or not to attract an atom nearby. A net dipole moment is created on a molecule due to the chemical polarity, which causes electrical charges to be separated, resulting in a positive and a negative end.

The electronegativity values of the atoms in a molecule can be used to determine the polarity of the molecule. As a means of maintaining their electrical arrangement, atoms have a tendency to draw the common pair of electrons closer to themselves.

The greater the amount of valence electrons and the greater the distance from the nucleus, the greater the electronegativity. The more valence electrons a substance has, the more likely it is to attract electrons and the greater its electronegativity value will be.

As a result, when the quantity of valence electrons is reduced, the electronegativity value will be lower and the electron attraction will be lower.

Methylamine (CH3NH2) is a polar molecule because the electronegativity discrepancies among the constituent atoms give rise to a dipole moment on the whole molecule. Carbon, hydrogen, and nitrogen have electronegativity values of 2.55, 2.20, and 3.04, respectively.

Because nitrogen’s electronegativity is greater than carbon’s, the dipole moment will shift towards nitrogen in carbon-nitrogen bonds. For nitrogen and hydrogen bonding, the dipole moment will again be added up because of the lone pair on nitrogen, but the dipole moment will go upward in that direction—the nitrogen atom’s upward motion.

In CH3NH2 methylamine (CH3NH2) the dipole moment will be strongest around nitrogen atom, which will lead to polarity in the molecule.

Furthermore, because the difference between the carbon and hydrogen atoms is so small, the bond is nonpolar in nature, but its intensity is far less than the dipole moment surrounding the nitrogen atom. As a result of this, methylamine (CH3NH2) has a polar character.


CH3NH2 (methylamine), which is the most common and least complex of the amines, is an excellent donor of electrons for bond formation. In order to understand the methylamine molecular structure, the Lewis structure was used to identify the two core atoms of the molecule.

It is also worth noting that the bond angles of the carbon and nitrogen atoms are sp3 hybridised, however nitrogen has a lone pair of electrons that deviate from the optimal proportion.

In addition, because of the strong dipole moment on the nitrogen atom and negligible on the carbon-hydrogen link, the methylamine molecule has a polar character.

Read more: Is PF3 Nonpolar or Polar?

Misha Khatri
Misha Khatri is an emeritus professor in the University of Notre Dame's Department of Chemistry and Biochemistry. He graduated from Northern Illinois University with a BSc in Chemistry and Mathematics and a PhD in Physical Analytical Chemistry from the University of Utah.


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