Is CH2Br2 a polar or a nonpolar compound?

Polarity is a fascinating and entertaining subject. If you want to study chemistry in college, this is an area you should pay attention to. We’ve been discussing comparable topics on our website since we like to make chemistry fun. In prior articles, we addressed questions such as ‘Is N2 Polar?’

We’ll see if CH2Br2 is polar or not in this article.

Is CH2Br2 nonpolar or polar? Due to the considerable difference in electronegativity of H (2.2) and Br (2.96) atoms, which gain partial positive and negative charge correspondingly, CH2Br2 (dibromomethane) is a polar molecule. CH2Br2 has a net dipole moment of 1.7 D, making it a polar molecule.

What causes CH2Br2 to be polar?

The Lewis structure of the response demonstrates the answer.

Two H-atoms and two Br-atoms are individually linked to the tetravalent carbon atom. Their electronegativities are substantially varied, despite the fact that their structure is symmetrical.

The electronegativity of the two bromines and two hydrogens differs because they are not opposite to each other.

This is how CH2Br2 acquires its polarity.

The Lewis structure of CH2Br2 is as follows:

What are Lewis Structures, exactly?

The number of valence electrons in a molecule is seen using dot structures of compounds. These structures aid in defining the compound’s overall polarity.

Steps to Determining Molecule Polarity

When electronegativity is not defined, how can you tell if a molecule is polar or not? Yes, it is correct.

Here are some guidelines to help you:

  1. Sketch out the Lewis Structure.
  2. Determine the shape of the molecule by using the VSEPR theory.
  3. Examine the dipole moment that results.
  4. It is non-polar when the resultant dipole moment is 0. It’s polar if it’s not zero.

What is the definition of polarity?

Polarity can exist in everything that carries a charge. The spatial difference of charges is polarity, often known as the dipole moment (=Qr) in a stricter sense.

There are two sorts of studies in polarity: bond polarity and molecule polarity.

What is the meaning of bond polarity?

Electronegativity difference causes an uneven distribution of charges across a bond. The element with the highest electronegativity holds electrons tightly.

A partially negative charge is acquired by an atom with a higher electron affinity during this process. A partially positive charge is acquired by an atom with a lower electron affinity.

For a bond to be polar, the difference in electronegativity must be more than 0.5.

The electronegativity values of the atoms in the bond can be used to determine the bond polarity.

Increased polarity forces the molecule to behave more ionically, whereas decreasing polarity forces the bond to behave more covalently.

Your Application Should Be Tested

Try to come up with a response to this question.

What is the most polar bond?





Halogens are one of the choices. F > Cl > Br > I is the electronegativity order of halogens. Fluorine and iodine’s bonds will be highly polarised because they are the most and least electronegative elements, respectively.

The most polar link is the I-F one.

What is the definition of Molecular Polarity?

It refers to the uneven distribution of charges in a molecule, similar to bond polarity.

Some atoms with a higher electron affinity attract electrons and receive a partial negative charge as a result. As a result, atoms with a lower electron affinity gain a partial positive charge.

The process of determining if a molecule is polar is more difficult.

When assessing whether a molecule is polar or not, compound structures are also taken into account. A thorough understanding of Lewis structures and VSEPR theory is required in this situation.

Theory of VSEPR

The Valence Shell Electron Repulsion Theory was presented by Sidgwick and Powell in 1940.

This is a chemical model for predicting a molecule’s overall shape. This model assumes that the final structure has the least amount of repulsion between electron pairs.

Postulates of the VSEPR Theory

• When there are more than three atoms in a molecule, a central atom is chosen. This is the atom that is bonded to other atoms.

• The number of valence shell electron pairs determines the molecule’s form.

• Because of the repulsion between electron pairs, the molecule tends to take on a structure with an orientation that minimises the repulsion experienced by each atom.

• The valence shell is a spherical space in which the electrons are arranged on the surface in such a way that the distance between them is as little as possible.

• When the centre atom has bond pair electrons surrounding it, it takes on an asymmetrical shape.

• When the core atom contains both bond pairs and lone pairs surrounding it, a deformed shape is expected.

• The VSEPR theory can also be used to molecular resonance structures. The following is the order of electron pair repulsion strength:

Lone pair – Lone pair > Lone pair – Bond pair > Bond pair – Bond pair – Bond pair – Bond pair – Bond pair – Bond pair – Bond pair – Bond pair – Bond pair –

• The reduced distance between electron pairs results in enhanced molecular energy. The repulsion between electron pairs increases as the distance between them gets shorter.

• The repulsion between electrons is reduced when they are separated by a greater distance. As a result, the molecule’s energy is low.

The Shapes of Molecules Can Be Predicted

In order to determine the shape of a molecule, the steps below must be followed.

• The atom with the least electron affinity is the centre atom. This is due to the fact that these atoms can more efficiently share electrons with others.

• Add one electron for each bonding atom to the number of valence electrons in the centre atom.

• Check the charge on the central metal atom; remove one electron if the central metal atom is positive. If the charge is negative, one electron should be added.

• Multiplying these two values by two yields the total number of electron pairs.

CH2Br2 is a chemical compound with the formula CH2Br2.

4 electrons of valence

4*1 = bonding electrons from four neighbouring atoms

(4 + 4)/2= 4 VSEPR Number

Tetrahedral, for example.

This value is useful in predicting shape. (Refer to the table below.)

The VSEP number is useful in estimating the molecule’s overall shape. The molecule is linear when the number is 2, trigonal planar when the number is 3, and so on.

Your Application Should Be Tested


Square Pyramidal Geometry

Polarity is a term that refers to the state of being


Tetrahedral geometry

Non-polarity is a type of polarity.

The polarity of CH2Br2 is determined by a number of factors.


A molecule’s polarity is measured by its dipole moment. We know from VSEPR postulates that as the dipole’s distance rises, polarity decreases. Similarly, when distance decreases, polarity increases.

Dibromomethane has a dipole moment of 1.7 D.

The polarity of the molecule is seen in the structure above. Two H and Br atoms are bonded to the core atom (carbon) and acquire partially positive and partially negative charges that do not cancel.

The bigger electronegativity gap between two atoms, the more polar the bond becomes.


This aspect in dibromomethane polarity is also explained by VSEPR theory.

We discovered that molecules align themselves in such a way that their electron pairs have the least repulsion.

Lone pairs are found on Bromine atoms rather than Carbon atoms in this chemical. As a result, it develops tetrahedral geometry.

The angle of the bond is 109 degrees.

Why is CCl4 non-polar and CH2Br2 polar, although having the same geometry?

In CCl4, the electronegativities of the four Cl atoms connected surrounding the C-atom cancel out, resulting in a non-polar structure.

The two Br and H atoms in CH2Br2, on the other hand, are not linked opposite one other, therefore their electronegativities do not cancel out, resulting in a polar structure.

Is the dipole affected by the presence of lone pairs?

The presence of lone pairs has no effect on the dipole moment, which is a measure of polarity.

Lone pairs, on the other hand, are particular cases when it comes to determining the overall shape of a molecule, which has an impact on the dipole.


In this post, we sought to clear up any confusion you may have about the idea of CH2Br2 polarity. Using two distinct polarity case studies, we demonstrated a simple approach to locating polarity.

We hope this has answered all of your queries about the concept. Our earlier articles focused on teaching the basics of polarity, such as “what is polarity?” and “factors impacting polarity.” As a result, the main focus of our article today was on determining polarity.

In order to determine polarity in molecules, this essay also stressed the study of Lewis dot structures and VSEPR theory.

The following are some major insights from this article:

The uneven distribution of spatial charge is referred to as polarity.

The electronegative difference must be 0.5 for the binding to be polar.

Bond polarity and molecular polarity are the two types of polarity.

Only the difference in electronegativity is considered when determining bond polarity.

To determine molecular polarity, geometry and Lewis dot structures are used.

The dipole moment is a measure of the compound’s polarity.

The length of the dipole also affects a molecule’s polarity.

Dipoles that are diametrically opposed cancel each other out.

Read more: Is Watermelon Acidic or Alkaline in pH?

Misha Khatri
Misha Khatri is an emeritus professor in the University of Notre Dame's Department of Chemistry and Biochemistry. He graduated from Northern Illinois University with a BSc in Chemistry and Mathematics and a PhD in Physical Analytical Chemistry from the University of Utah.


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